STYRENE MONOMER : ENVIRONMENTAL, HEALTH & SAFETY Guidelines
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2. Product Information and Characteristics

2.2. Physical Properties

Table 1: Typical Physical Properties.

Property Common Usage
Value & Unit
International System
Value & Unit
Physical Form Colourless, oily liquid  
Colour (acc. ASTM D 1209 / DIN 6271) 10 max. / Pt-Co scale  
Odour Unpleasant, aromatic  
Odour threshold 0.1 ppm 0.43 mg/m3
Relative molecular mass 104.14  
Density at 20°C (acc. ASTM D 4052 0.906 kg/l 906 kg/m3
Boiling point  V 145°C
Melting point/Freezing point  V -31°C
Kinematic viscosity at 0°C 1.1 cSt 1.1 mm2/s
Kinematic viscosity at 20°C 0.8 cSt 0.8 mm2/s
Kinematic viscosity at 40°C 0.6 cSt 0.6 mm2/s
Kinematic viscosity at 100°C 0.4 cSt 0.4 mm2/s
Vapour density (air =1) 3.6  
Vapour pressure at 20°C 6 mbar 0.6 kPa
Vapour pressure at 50°C 32 mbar 3.2 kPa
Vapour pressure at 80°C 121.2 mbar 12.12 kPa
Conductivity, thermal at 20°C 1.6x10-3 J/(s.cm.K) 0.16 W/m°C
Flash point (ABEL; acc. IP 170)  VV 31-32°C
Autoignition temperature  VV 490°C
Saturation concentration in air at 20°C 5923 ppm (v/v) 25.6 g/cm3
Explosion limits in air 0.9 - 6.8% vol.  
Miscibility in water immiscible  
Solubility in water at 20°C 0.029% wt./vol. 0.29 kg/m3
Solubility of water in substance at 20°C 0.054% wt./vol. 0.54 kg/m3
Coefficient of Expansion at 20°C V 0.979x10-3/°C
Specific heat at 20°C  V 1.73 kJ/kg.°C
Heat of combustion, Hc at 25°C -1018.83 kcal/mole -4265.64 kJ/mole
Heat of formation, Hf, gas at 25°C 35.22 kcal/mole 147.46 kJ/mole
Heat of formation, Hf, liquid at 25°C 24.72 kcal/mole 103.50 kJ/mole
Heat of polymerisation, Hp at 25°C -16.88 kcal/mole -70.67 kJ/mole
Refractive index 1.546 (nD at 20°C) V
Rel. evaporation rate (di-ethylether = 1 min.) 12.4  
Source: CEFIC Styrene Distribution Group
 
 

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